Cool Stars 14 - Submitted Abstract # 115 This version created on 05 October 2006 First detection of molecular circular polarization in starspots S.V. Berdyugina, Institute of Astronomy ETH Zurich P. Petit, Observatoire Midi-Pyrenees, Toulouse D.M. Fluri, Institute of Astronomy ETH Zurich N. Afram, Institute of Astronomy ETH Zurich J. Arnaud, Observatoire Midi-Pyrenees, Toulouse We report on the first ever detection of circular polarization in molecular lines forming in magnetic regions on the surfaces of active stars. The new observations were obtained with the high-resolution spectro-polarimeter ESpADOnS recently installed at the Canada-France-Hawaii Telescope. We carried out a survey of G-K-M stars including young main-sequence dwarfs and RS CVn-type giants and subgiants. All stars were found to possess surface magnetic fields producing Stokes V LSD signals in atomic lines of 0.05% to 0.5%. Several stars clearly showed circular polarization in molecular lines of 0.5% to 1%. The molecular Stokes V signal is reminiscent to that observed in sunspots. Modeling the observed polarization allows us for the first time to diagnose the magnetic field in the coolest parts of spatially unresolved starspots and reveal their internal structure. ----------------------------------